Orange/white should be your incoming line ( green/black is usually spare for 2nd line )just connect orange ( A ) to no.5 and white ( B ) to no.2
I,m afraid I don't have a white cable. My four are Brown Blue Orange & Green. This is definitely the master socket, but it is in a purpose built flat if that makes any difference. The flat was built in the early 1970,s. Any GPO people around from that era who may be able to help?