Hi @Silentbob welcome to the community and thanks for posting, the call waiting is a feature controlled on the mobile handset so you need to activate it in the call settings.
Turn call waiting on or off : Samsung Galaxy A5
- Find "More settings" Press Phone. Press Keypad. Press the menu icon. ...
- Turn call waiting on or off. The current settings are displayed. Press Call waiting to turn the function on or off.
- Return to the home screen. Press the Home key to return to the home screen