Are you connecting the NAS to an Ethernet port or the USB port? It would be normal to connect a NAS to an Ethernet port. Its not really a NAS per se if you intend to just connect a USB device to the hub.
If you do just intend to connect USB device, it will be extremely slow as the USB port is only USB2 and also you will need to enable SMB1 in your devices
My NAS plugs into an ethernet port, works fine.