Make sure yu are using the Wireless passkey/password and not the Admin password.
It may be that the Smarthub is not a new one and is a "refurbished" one. Try a factory reset of the Smarthub by pressing a pin into the recess button on the rear for about 20 seconds. This should restore the wireless password to the one on the label.
'Tis a new hub.
Connected PC and Roku box using WAP button.
iPlayer accepted password.
TV accepted password.
Everything now hunky dory.
Just wish BT/EE would make the font larger on the little sticker.